catena-Poly[[(1,10-phenanthroline-κ2 N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ4 O 2,O 2′:O 5,O 5′]
نویسندگان
چکیده
In the title coordination polymer, [Zn(C(6)H(2)O(5))(C(12)H(8)N(2))](n), an infinite chain is formed along [010] by linking the chelated {Zn(phen)} entities (phen is 1,10-phenanthroline) with two carboxyl-ate groups of the furan-2,5-dicarboxyl-ate ligand. The Zn(II) atom shows trigonal-prismatic coordination.
منابع مشابه
catena-Poly[[(1,3-dimethylimidazolin-2-one-κN)(1,10-phenanthroline-κ2 N,N′)copper(II)]-μ-furan-2,5-dicarboxylato-κ2 O 2:O 5]
The polymeric title compound, [Cu(C(6)H(2)O(5))(C(12)H(8)N(2))(C(5)H(10)N(2)O)](n), is composed of an infinite chain formed along [100] by linking the (1,3-dimethyl-imidazolin-2-one)(1,10-phenanthroline)copper(II) units with two O atoms of two carboxyl-ate groups of the furan-2,5-dicarboxyl-ate ligand. The Cu(II) atom, which lies on a twofold rotation axis, displays a square-pyramidal coordinat...
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In the title compound, [Mn(2)(C(10)H(4)O(8))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](n), the Mn(2+) ion has a slightly distorted octa-hedral N(2)O(4) coordination geometry being coordinated by one aqua O atom, two N atoms of the chelating 1,10-phenanthroline ligand and three carboxyl O atoms from three 2,5-dicarb-oxy-benzene-1,4-dicarboxyl-ate (H(2)btec(2-)) ligands. The H(2)btec(2-) anion exhibits two...
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In the crystal structure of the title compound, {[Cu(C(8)H(6)O(9))(C(12)H(8)N(2))]·0.69H(2)O}(n), the Cu(II) atom has a distorted octa-hedral geometry, coordinated by four O atoms from two 3,4-dicarboxy-tetra-hydro-furan-2,5-dicarboxyl-ate ligands and two N atoms from one 1,10-phenanthroline ligand. One of the carboxylate groups bridges the Cu(II) atoms, forming a zigzag chain running along the...
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The asymmetric unit of the title compound, {[Cu2(C6H2O5)2(C12H8N2)2(H2O)3]·C3H7NO} n , contains two Cu(II) atoms, two furan-2,5-dicarboxyl-ate (L) ligands, two 1,10-phenanthroline (phen) ligands, three coordinating water mol-ecules and one N,N-dimethyl-formamide solvent mol-ecule. Each Cu(II) atom is coordinated by two N atoms from one phen ligand, two O atoms from two L ligands and two water m...
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In the title complex, {[Zn(C(7)H(3)NO(4))(C(12)H(8)N(2))]·H(2)O}(n), the Zn(II) ion is in a distorted octa-hedral environment, defined by two N atoms from a chelating 1,10-phenanthroline (phen) ligand and one N atom and three O atoms from two pyridine-2,3-dicarboxyl-ate (2,3-pydc) ligands. The bridging 2,3-pydc ligands connect the Zn(II) ions into a chain extending along [010]. O-H⋯O hydrogen b...
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